Primary receptacles must be further packed in non-specification bulk outer packagings such as cubic yard boxes, plastic rigid-wall bulk containers, dump trailers, and roll-off containers. The proper shipping name Paint related material may be used for consignments of packages containing Paint and Paint related material in the same package; b. 386 When transported by private motor carrier only, the following corrosive liquids may be packaged in polyethylene bottles with a capacity no greater than 3.785 L (one gallon), further packed inside an open-top, heavy wall, high density polyethylene box (i.e., crate) in a manner that the polyethylene bottles are not subjected to any superimposed weight, and the boxes must be reasonably secured against shifting within the transport vehicle and loaded so as to minimize the possibility of coming in contact with other lading: Compounds, cleaning liquid, NA1760, PG II or III; Corrosive liquid, acidic, inorganic, n.o.s., UN3264, PG II; Corrosive liquid, acidic, organic, n.o.s., UN3265, PG III; Corrosive liquid, basic, inorganic, n.o.s., UN3266, PG II; Hydrochloric acid solution, UN1789, PG II; and. 384 For green graphite electrodes and shapes that are large single component solid objects not subject to shifting, transport in open rail flat cars, open bed motor vehicles, and intermodal containers is also authorized. These provisions apply only to non-bulk packagings: N3 Glass inner packagings are permitted in combination or composite packagings only if the hazardous material is free from hydrofluoric acid. B69 Dry sodium cyanide or potassium cyanide may be shipped in the following sift-proof and weather-resistant packagings: metal covered hopper cars, covered motor vehicles, portable tanks, or non-specification bins. 37 Unless it can be demonstrated by testing that the sensitivity of the substance in its frozen state is no greater than in its liquid state, the substance must remain liquid during normal transport conditions. Further, the limitations and/or additional requirements found in the special provisions of column 7 will supersede the packaging authorizations of column 8 of the Hazardous Materials Table. 379 When offered for transport by highway, rail, or cargo vessel, anhydrous ammonia adsorbed or absorbed on a solid contained in ammonia dispensing systems or receptacles intended to form part of such systems is not subject to the requirements of this subchapter if the following conditions in this provision are met. N75 Packages consisting of tightly closed inner packagings of glass, earthenware or metal, securely cushioned and packed in outer wooden barrels or wooden or fiberboard boxes, capacity not over 2.5 kg (5.5 pounds) net weight, are authorized and need not conform to the requirements of part 178 of this subchapter. Nickel-metal hydride batteries subject to this special provision are subject only to the following requirements: (1) The batteries must be prepared and packaged for transport in a manner to prevent a dangerous evolution of heat, short circuits, and damage to terminals; and are subject to the incident reporting in accordance with 171.16 of this subchapter if a fire, violent rupture, explosion or dangerous evolution of heat (i.e., an amount of heat sufficient to be dangerous to packaging or personal safety to include charring of packaging, melting of packaging, scorching of packaging, or other evidence) occurs as a direct result of a nickel metal hydride battery; and (2) when loaded in a cargo transport unit in a total quantity of 100 kg gross mass or more, the shipping paper requirements of Subpart C of this part, the manifest requirements of 176.30 of this subchapter, and the vessel stowage requirements assigned to this entry in Column (10) of the 172.101 Hazardous Materials Table. How to Read the Hazardous Materials Table B53 Packagings must be made of either aluminum or steel. For this test, the provisions of paragraphs 16.6.1.2 except letter g, 16.6.1.3.1 to 16.6.1.3.6, 16.6.1.3.7(b) and 16.6.1.3.8 of the UN Manual of Tests and Criteria must be applied. 163 Substances must satisfactorily pass Test Series 8 of the UN Manual of Tests and Criteria, Part I, Section 18 (IBR, see 171.7 of this subchapter). Lithium batteries installed in a cargo transport unit, designed only to provide power external to the transport unit must use the proper shipping name Lithium batteries installed in cargo transport unit found in the 172.101 Hazardous Materials Table. (c) Tables of special provisions. Ch 6.0b Flashcards | Quizlet If a vehicle is powered by a flammable liquid and a flammable gas internal combustion engine, it must be described using Vehicle, flammable gas powered. This includes hybrid electric vehicles powered by both an internal combustion engine and wet, sodium or lithium batteries installed. A189 Except where the defining criteria of another class or division are met, concentrations of formaldehyde solution: a. Lead-free Solder Figure 3: Engineer soldering a microcircuit Note, Tin here is the primary metal. Organization and Purpose After unloading, the residual material also must be covered with an inert gas or the container must be filled with water to the tank's capacity. B8 Packagings shall be made of nickel, stainless steel, or steel with nickel, stainless steel, lead or other suitable corrosion resistant metallic lining. Column 7 specifies codes for special provisions applicable to hazardous materials. 64 The group of alkali metals includes lithium, sodium, potassium, rubidium, and caesium. (6) R codes. Insulating materials may not promote corrosion to steel when wet. Unfortunately, the amendments to the table entries for various hazardous materials introduced new unintended errors that PHMSA is correcting in this notice. (v) UN and IM portable tank codes/special provisions. A3 For combination packagings, if glass inner packagings (including ampoules) are used, they must be packed with absorbent material in tightly closed rigid and leakproof receptacles before packing in outer packagings. TP17 Only inorganic non-combustible materials may be used for thermal insulation of the tank. B28 Packagings must be made of stainless steel. The vacant space (outage) may be charged with a nonflammable nonliquefied compressed gas if the pressure in the cylinder or sphere at 55 C (130 F) does not exceed 125 percent of the marked service pressure. A191 Notwithstanding the Division 6.1 subsidiary risk for this description, the toxic subsidiary risk label and the requirement to indicate the subsidiary risk on the shipping paper are not required for manufactured articles containing less than 5 kg (11 pounds) of mercury. The capacity of each drum must not exceed 220 L (58 gallons). W41 When offered for transportation by water, this material must be packaged in bales and be securely and tightly bound with rope, wire or similar means. N91 The use of a non specification sift-proof, non-bulk, metal can with or without lid, or a non specification sift-proof, non-bulk fiber drum, with or without lid is authorized when transporting coal tar pitch compounds by motor vehicle or rail freight. How to Use Hazmat Special Provisions | Lion Technology B45 Each tank must have a reclosing combination pressure relief device equipped with stainless steel or platinum rupture discs approved by the AAR Tank Car Committee. 345 Nitrogen, refrigerated liquid (cryogenic liquid), UN1977 transported in open cryogenic receptacles with a maximum capacity of 1 L are not subject to the requirements of this subchapter. Transport in accordance with this special provision must be noted on the shipping paper. (a) The Hazardous Materials Table . This may be fulfilled by an additional locking device linked to the activator; (4) Each article must be manufactured in such a way as to prevent hazardous projections of the pressure receptacle or parts of the pressure receptacle; (5) Each pressure receptacle must be manufactured from material which will not fragment upon rupture; (6) The design type of the article must be subjected to a fire test. 51 This description applies to items previously described as Toy propellant devices, Class C and includes reloadable kits. W8 Vessel stowage category for pyrophoric thorium metal or pyrophoric uranium metal is D as defined in 172.101(k)(4). While columns 8 and 7 of the Hazardous Materials Table are used to determine authorized packaging for most HazMat (more on that in a little bit), some methods of transportation, HazMat quantities, and specific operations rely on other methods. 45 Temperature should be maintained between 18 C (64.4 F) and 40 C (104 F). If a tank car tank is equipped with a reclosing pressure relief valve, the tank must also be equipped with a vacuum relief valve. N40 This material is not authorized in the following packagings: a. If one of the components, which can be a pure substance or a mixture, is classed as flammable, the chemical under pressure must be classed as flammable in Division 2.1. Formaldehyde solutions not containing methanol and not meeting the Class 3 flammable liquid criteria must be described using a different proper shipping name. 62 Oxygen generators (see 171.8 of this subchapter) are not authorized for transportation under this entry. The material is also be subject to operational controls which include not exceeding a temperature of 55C (130F) at the time it is offered or during transportation, not exceeding a transportation time of 24 hours, and drivers transporting spent bleaching earth must be trained in the properties and hazards of the spent bleaching earth. 15, 1976, unless otherwise noted. (4) A code containing the letters IB or IP refers to a special provision that applies only to transportation in IBCs. When a plus sign is assigned to mix- A35 This includes any material which is not covered by any of the other classes but which has an anesthetic, narcotic, noxious or other similar properties such that, in the event of spillage or leakage on an aircraft, extreme annoyance or discomfort could be caused to crew members so as to prevent the correct performance of assigned duties. B133 Hydrochloric acid concentration not exceeding 38%, in Packing Group II, is authorized to be packaged in UN31H1 or UN31HH1 intermediate bulk containers when loaded in accordance with the requirements of 173.35(h) of this subchapter. For transportation by aircraft, as an inner packaging of a combination packaging with a maximum gross mass of 30 kg when packaged as a limited quantity in accordance with 173.27(f). No outage is required for helium. 353 Ammonium permanganate, ammonium permanganate aqueous solutions, and mixtures of a permanganate with an ammonium salt are forbidden for transport. US DOT's Hazardous Materials Regulations (HMR) list more than 3,000 shipping names for regulated materialsfrom acetal to zirconium tetrachloride. Energy storage capacity means the energy held by a capacitor, as calculated using the nominal voltage and capacitance. 49 CFR -172.101 Hazardous Materials Table info - MaselliWeb The shipper must ensure that all applicable requirements of 173.185 of this subchapter are met. TP26 The heating device must be exterior to the shell. (vi) Except when an organic peroxide is authorized under 173.225(g), if a hazardous material is not assigned a portable tank T Code, the hazardous material may not be transported in a portable tank unless approved by the Associate Administrator. The toy plastic or paper caps must be in the form of sheets, strips, rolls, or individual caps; b. A bulk packaging containing sulfur is not subject to the placarding requirements of subpart F of this part, if it is marked with the appropriate identification number as required by subpart D of this part. The only tank car tanks authorized are Class DOT 105 tank cars having a test pressure of 2,069 kPa (300 psig) or greater. Individual Name: Mr. David Comen. If you have comments or suggestions on how to improve the www.ecfr.gov website or have questions about using www.ecfr.gov, please choose the 'Website Feedback' button below. Stacking is permitted two or more levels high to achieve maximum allowable utilization of the designated vehicle, rail car weight, or intermodal freight container weight or vessel hold volume. Column 2 specifies the minimum test pressure, in bar (1 bar = 14.5 psig), at which the periodic hydrostatic testing required by 180.605 of this subchapter must be conducted. The suitability for transport in tanks must be demonstrated using test 8(d) in Test Series 8 (see UN Manual of Tests and Criteria, Part 1, Sub-section 18.7) (IBR, see 171.7 of this subchapter) or an alternative means approved by the Associate Administrator. Additionally, unless otherwise excepted in this subchapter, polyester resin kits must be packaged in specification combination packagings based on the performance level of the base material contained within the kit. Lading in unlined tanks must be inhibited so that the corrosive effect on steel is not greater than that of hydrofluoric acid of 65 percent concentration. The lithium batteries must meet the requirements of 173.185(a) and contain the necessary systems to prevent overcharge and over discharge between the batteries. Column 7 of the HMT specifies codes for special provisions applicable to packaging, packaging requirements, certification, and marking or labeling for a hazardous material. 167 These storage systems must always be considered as containing hydrogen. authorized by name in the Hazardous Materials Table or have been specifically authorized by name either in the Section 172.101 Hazardous Materials Table or have been assigned a shipping name and hazard class by the Associate Administrator for Hazardous Materials Safety. d. A chemical under pressure with components meeting the properties of: Class 1 (explosives); Class 3 (liquid desensitized explosives); Division 4.1 (self-reactive substances and solid desensitized explosives); Division 4.2 (substances liable to spontaneous combustion); Division 4.3 (substances which, in contact with water, emit flammable gases or toxic gases); Division 5.1 (oxidizing substances); Division 5.2 (organic peroxides); Division 6.2 (Infectious substances); or, Class 7 (Radioactive material), must not be offered for transportation under this description. Metal: 11A, 11B, 11N, 21A, 21B and 21N, b. Codes in Column 7 may be numbers, or a combination of letters and numbers. Your Nuclear Attack Map for 2023 - mirasafety.com This content is from the eCFR and may include recent changes applied to the CFR. Thickness of stainless steel for portable tank shells and heads must be the greater of 6.35 mm (0.250 inch) or the thickness required for a portable tank with a design pressure at least equal to 1.3 times the vapor pressure of the hazardous material at 46 C (115 F). R1 A person who offers for transportation tank cars containing sulfur, molten or residue of sulfur, molten may reference the Sulfur Institute's, Molten Sulphur Rail Tank Car Guidance document (see 171.7 of this subchapter) to identify tank cars that may pose a risk in transportation due to the accumulation of formed, solid sulfur on the outside of the tank. 78 This entry may not be used to describe compressed air which contains more than 23.5 percent oxygen. Displaying title 49, up to date as of 3/02/2023. 120 The phlegmatized substance must be significantly less sensitive than dry PETN. user convenience only and is not intended to alter agency intent 340 This entry applies only to the vessel transportation of nickel-metal hydride batteries as cargo. 389 This entry only applies to lithium ion batteries or lithium metal batteries installed in a cargo transport unit and designed only to provide power external to the cargo transport unit. B77 Other packaging are authorized when approved by the Associate Administrator. A copy of the approval must accompany each shipment. (9) A code containing the letter W refers to a special provision that applies only to transportation by water. TP19 The calculated wall thickness must be increased by 3 mm at the time of construction. The objects must be secured to the flat car, motor vehicle, intermodal container, or unitized by steel banding to wooden runners or pallets and the units secured to the flat car, motor vehicle, or freight container to prevent shifting, including relative motion between the objects, under conditions normally incident to transportation. Mass detonate means more than 90 percent of the devices tested in a package explode practically simultaneously. 196 The nitrocellulose must meet the criteria of the Bergmann-Junk test or methyl violet paper test in the UN Manual of Tests and Criteria, Appendix 10 (IBR, see 171.7 of this subchapter). Solids meeting the definition of an elevated temperature material must be transported in accordance with the applicable requirements of this subchapter. N12 Plastic packagings are not authorized. 108 Fireworks must be so constructed and packaged that loose pyrotechnic composition will not be present in packages during transportation. B76 Tank cars constructed before March 16, 2009, must have a test pressure of 20.68 Bar (300 psig) or greater and conform to Class 105S, 112J, 114J or 120S. (2) A code containing the letter A refers to a special provision which applies only to transportation by aircraft. Except for transportation by aircraft, in palletized loads, a pallet box or unit load device (e.g. For criteria in determining what is a new lighter design, see 173.308(b)(1). The rechargeable (and some non-rechargeable) types have gelled alkaline electrolytes (rather than acidic) making it difficult for them to generate hydrogen or oxygen when overcharged and therefore, differentiating them from non-spillable batteries. The receptacles must be constructed with glass double walls having the space between the walls vacuum insulated and each receptacle must be transported in an outer packaging with sufficient cushioning and absorbent materials to protect the receptacle from damage. A separate drafting site (8) A code containing the letters TP refers to a portable tank special provision for UN or IM Specification portable tanks that is in addition to those provided by the portable tank instructions or the requirements in part 178 of this subchapter. In addition, there are over 300 numeric codes provisions. Furthermore, lithium batteries installed in a cargo transport unit, designed only to provide power external to the transport unit must be described using the proper shipping name Lithium batteries installed in cargo transport unit found in the 172.101 Hazardous Materials Table. Table 1 authorizes IBCs for specific proper shipping names through the use of IB Codes assigned in the 172.101 table of this subchapter. 55 This device must be approved in accordance with 173.56 of this subchapter by the Associate Administrator. N76 For materials of not more than 25 percent active ingredient by weight, packages consisting of inner metal packagings not greater than 250 mL (8 ounces) capacity each, packed in strong outer packagings together with sufficient absorbent material to completely absorb the liquid contents are authorized and need not conform to the requirements of part 178 of this subchapter. Each IBC may not exceed a maximum net quantity of 1,000 kg: a. TP12 This material is considered highly corrosive to steel. When no IB code is assigned in the 172.101 Table for a specific proper shipping name, or in 173.185 or 173.225(e) Organic Peroxide Table for Type F organic peroxides, use of an IBC or Large Packaging for the material may be authorized when approved by the Associate Administrator. TP7 The vapor space must be purged of air by nitrogen or other means. Unless otherwise provided in this subchapter, these special provisions do not apply to UN, IM Specification portable tanks or IBCs. The tank car specification may be marked to indicate a test pressure of 20.68 Bar (300 psig). See 173.306(h) of this subchapter. (c) Additional air transport requirements. B3 MC 300, MC 301, MC 302, MC 303, MC 305, and MC 306 and DOT 406 cargo tanks and DOT 57 portable tanks are not authorized. We recommend you directly contact the agency responsible for the content in question. For transportation by aircraft, articles, machinery, or apparatus, may not contain any material forbidden for transportation by passenger or cargo aircraft. A rocket motor to be considered nonpropulsive must be capable of unrestrained burning and must not appreciably move in any direction when ignited by any means. e. A description to which special provision 170 or TP7 is assigned in Column 7 of the 172.101 Hazardous Materials Table, and therefore requires air to be eliminated from the package vapor space by nitrogen or other means, must not be offered for transportation under this description. 420 This entry does not apply to manufactured articles (such as table tennis balls). N90 Metal packagings are not authorized. A7 Steel packagings must be corrosion-resistant or have protection against corrosion. eCFR :: 49 CFR 172.102 -- Special provisions. Packagings must be so constructed that explosion is not possible by reason of increased internal pressure. B2 MC 300, MC 301, MC 302, MC 303, MC 305, and MC 306 and DOT 406 cargo tanks are not authorized. (v) The box must be constructed from high-density polyethylene in the density range 0.950-0.962, and be capable of holding liquid when in the upright position. a. Placards may be displayed for a hazardous material, even when not required, if the placarding otherwise conforms to the requirements of Subpart F of Part 172 [172.502(c)]. c. The cylinders are collected and transported by a private or a contract carrier for reconditioning, reuse or disposal. 114 Jet perforating guns, charged, oil well, without detonator may be reclassed to Division 1.4 Compatibility Group D (1.4D) if the following conditions are met: a. A13 Bulk packagings are not authorized for transportation by aircraft. eCFR :: 49 CFR 172.101 -- Purpose and use of hazardous materials table. (ii) One bottle for every two hours of production, or for every 2,500 bottles produced, must be tested by dropping a bottle filled to 98 percent capacity with water from a height of 1.2 meters (3.9 feet) onto solid concrete directly on the closure. Flexible, fiberboard or wooden IBCs must be sift-proof and water-resistant or be fitted with a sift-proof and water-resistant liner. will bring you to those results. It is shown that it does not pose a significant risk in transportation; b. W10 When offered for transportation by vessel, the use of Large Packagings (see 171.8 of this subchapter) is prohibited. Company Name: Artisan EHS Consulting, LLC. In addition, packages shall be legibly and durably marked with an identification of the consignor, the consignee, or both. These requirements must be met in addition to the design and construction specifications in part 178 of this subchapter. 2 Except when authorized under Special Provision 41. Single unit tank car tanks must have a reclosing pressure relief device having a start-to-discharge pressure set at no more than 1551 kPa (225 psig). What is Column 7 of the hazardous materials Table? The outside of each package must be plainly marked ARTICLES, EXPLOSIVES, N.O.S. 160 This entry applies to safety devices for vehicles, vessels or aircraft, e.g. All special provision (iii) A copy of the test results must be kept on file at each facility where packagings are offered for transportation, and must be made available to a representative of the Department upon request.
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